As n8n does use Pyodide underneath the hood, which does not support the request module, does sadly n8n neither. So, I suggest using the HTTP Request Node to make HTTP requests.
Regarding your second question, assuming you have Mode: Run Once for Each Item set, you should actually be able to see the answer in the default code of a Code node.
The default code is:
# Add a new field called 'myNewField' to the JSON of the item
_input.item.json.myNewField = 1
return _input.item
Meaning assuming the “ASIN” is saved as asin on the item, you can access it via _input.item.json.asin.